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This book presents materials fundamentals of novel gate dielectrics that are being introduced into semiconductor manufacturing to ensure the continuous scalling of the CMOS devices. This is a very fast evolving field of research so we choose to focus on the basic understanding of the structure, thermodunamics, and electronic properties of these materials that determine their performance in device applications. Most of these materials are transition metal oxides. Ironically, the d-orbitals responsible for the high dielectric constant cause sever integration difficulties thus intrinsically limiting high-k dielectrics. Though new in the electronics industry many of these materials are wel known in the field of ceramics, and we describe this unique connection. The complexity of the structure-property relations in TM oxides makes the use of the state of the art first-principles calculations necessary. Several chapters give a detailed description of the modern theory of polarization, and heterojunction band discontinuity within the framework of the density functional theory. Experimental methods include oxide melt solution calorimetry and differential scanning calorimetry, Raman scattering and other optical characterization techniques, transmission electron microscopy, and x-ray photoelectron spectroscopy.

Advanced Quantum Mechanics, the second volume on quantum mechanics by Franz Schwabl, discusses nonrelativistic multi-particle systems, relativistic wave equations and relativistic fields. Characteristic of Schwabl’s work, this volume features a compelling mathematical presentation in which all intermediate steps are derived and where numerous examples for application and exercises help the reader to gain a thorough working knowledge of the subject. The treatment of relativistic wave equations and their symmetries and the fundamentals of quantum field theory lay the foundations for advanced studies in solid-state physics, nuclear and elementary particle physics. This text extends and complements Schwabl’s introductory Quantum Mechanics, which covers nonrelativistic quantum mechanics and offers a short treatment of the quantization of the radiation field. New material has been added to this third edition of Advanced Quantum Mechanics on Bose gases, the Lorentz covariance of the Dirac equation, and the ‘hole theory’ in the chapter "Physical Interpretation of the Solutions to the Dirac Equation."

Research in the field of shock physics and ballistic impact has always been intimately tied to progress in development of facilities for accelerating projectiles to high velocity and instrumentation for recording impact phenomena. The chapters of this book, written by leading US and European experts, cover a broad range of topics and address researchers concerned with questions of material behaviour under impulsive loading and the equations of state of matter, as well as the design of suitable instrumentation such as gas guns and high-speed diagnostics. Applications include high-speed impact dynamics, the inner composition of planets, syntheses of new materials and materials processing. Among the more technologically oriented applications treated is the testing of the flight characteristics of aeroballistic models and the assessment of impacts in the aerospace industry.

Optoelectronic devices transform electrical signals into optical signals (and vice versa) by utilizing the interaction of electrons and light. Advanced software tools for the design and analysis of such devices have been developed in recent years. However, the large variety of materials, devices, physical mechanisms, and modeling approaches often makes it difficult to select appropriate theoretical models or software packages. This book presents a review of devices and advanced simulation approaches written by leading researchers and software developers. It is intended for scientists and device engineers in optoelectronics who are interested in using advanced software tools. Each chapter includes the theoretical background as well as practical simulation results that help the reader to better understand internal device physics. Real-world devices such as edge-emitting or surface-emitting laser diodes, light-emitting diodes, solar cells, photodetectors, and integrated optoelectroniccircuits are investigated. The software packages described in the book are available to the public, on a commercial or noncommercial basis, so that the interested reader is quickly able to perform similar simulations.

Since the first papers by E. N. Leith and J. Upatnieks on the subject of holography appeared in 1961, there has been a virtual explosion of research activity in the field. More than 500 papers and articles on holo­ graphy have appeared in the last ten years. Many applications of holo­ graphy have been proposed, and some of these are beginning to enter the realm of usefulness. One of the applications that appears to hold great promise is acoustic imaging by means of holography. The first papers on this subject appeared in 1966, but already research activity in the field is burgeoning. Three symposia wholly devoted to acoustical holography have been held and the papers published in book form. The purposeof this book is to bring together the results of research in acoustical holography, some of it as yet unpublished, under one cover so that workers in holography, nondestructive testing, medical imaging, underwater imaging, and seismic exploration can decide whether this new technique can be useful to them.

to arrive at some temporary consensus model or models; and to present reliable physical data pertaining to water under a range of conditions, i.e., "Dorsey revisited," albeit on a less ambitious scale. I should like to acknowledge a debt of gratitude to several of my col­ leagues, to Prof. D. J. G. Ives and Prof. Robert L. Kay for valuable guidance and active encouragement, to the contributors to this volume for their willing cooperation, and to my wife and daughters for the understanding shown to a husband and father who hid in his study for many an evening. My very special thanks go to Mrs. Joyce Johnson, who did all the cor­ respondence and much of the arduous editorial work with her usual cheerful efficiency. F. FRANKS Biophysics Division Unilever Research Laboratory ColworthjWelwyn Colworth House, Sharnbrook, Bedford March 1972 Contents Chapter 1 Introduction-Water, the Unique Chemical F. Franks I. lntroduction …………………………………. . 2. The Occurrence and Distribution of Water on the Earth 2 3. Water and Life ……………………………….. 4 4. The Scientific Study of Water-A Short History …….. 8 5. The Place of Water among Liquids . . . . . . . . . . . . . . . 13 . . . . . Chapter 2 The Water Moleeule C. W. Kern and M. Karplus 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 . . . . . . . . . . 2. Principles of Structure and Spectra: The Born-Oppenheimer Separation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 . . . . . . . . . . . . 3. The Electronic Motion …………………………. 26 3.1. The Ground Electronic State of Water ………… 31 3.2. The Excited Electronic States of Water ……….. 50 4. The Nuclear Motion …………………………… 52 5.External-Field Effects …………………………… 70 5.1. Perturbed Hartree-Fock Method.